I assume steam rain refers to the droplets of water from the steam vent that has a silencer? Normally its pretty high up and directed away from where people will walk. The droplets are not harmful and are not hot, just slightly warm by the time they reach the ground. Most people wont feel anything as they will likely be wearing clothes and other PPE when they walk by. Even if it did drop on them, its too small to feel.
Most of the steam will remain as steam and rise up, even during larger venting it definitely wont be pouring hot boiling water to the people below.
The amount of droplets formed is about proportional to the pressure of the vessel it vents from. The higher the pressure the lesser the droplets.(Although there are quite a number of other factors like piping and equipment in between).
As to the calculation, is it really necessary? The amount of droplets formed is minuscule as compared to the amount of vented steam and depends on quite a number of factors and assumptions, to the point that any calculation would likely have large amounts of error. If you are really worried, you can place a bib just below the vent and drain the condensate to the ground by a tubing.
Edited by thorium90, 20 February 2013 - 10:04 AM.